An imidazolium-functionalized self-assembling calix[4]pyrrole.
نویسندگان
چکیده
A calixpyrrole bearing a tethered imidazolium functional group was prepared in the form of its bromide salt. This compound was found to undergo self-assembly to produce supramolecular polymers, wherein both the bromide anion and the imidazolium cation are bound to the calixpyrrole core.
منابع مشابه
Molecular recognition and self-assembly special feature: Self-assembly of dimeric tetraurea calix[4]pyrrole capsules.
Calix[4]pyrroles having extended aromatic cavities have been functionalized with 4 ureas in the para position of their meso phenyl substituents. This elaboration of the upper rim was completed in 2 synthetic steps starting from the alpha,alpha,alpha,alpha-tetranitro isomer of the calix[4]pyrrole obtained in the acid catalyzed condensation of p-nitrophenyl methyl ketone and pyrrole. In dichlorom...
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 88 شماره
صفحات -
تاریخ انتشار 2014